Access to a CuII–O–CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Myochrysine Solution Structure and Reactivity

We have determined the framework structure of Myochrysine (disodium gold(I)thiomalate) in the solid state and extremely concentrated aqueous solution, previously. It consists of an open chain polymer with linear gold coordination to two thiolates from the thiomalic acid moieties which bridge between pairs of gold atoms providing an Au-S-Au angle of 95 degrees . The question remained: was this s...

متن کامل

Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex.

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.

متن کامل

Structure Exploring, IR and UV Spectroscopic Properties of Pomalidomide as a Second-generation of Immunomodulatory Agent

In this article, the optimized geometry, IR and UV spectra, frontier orbital analysis, natural bond orbital (NBO) analyses, and thermodynamic parameters of pomalidomide were investigated. The calculated structural parameters and stretching frequencies values are compared with experimentalvalues of the investigated compound. Also, the relations of the thermodynamic functions vs.temperatures were...

متن کامل

Spectroscopic Studies to establish Relationships between Structure , Bonding and Reactivity in Selected Inorganic Species

This thesis explores the influence of molecular and electronic structure on the reactivity of some small inorganic complexes, beginning with a review of the nature and properties of metal-hydrogen and metal-carbon bonds of early transition metals and of their importance in catalysis. A series of cationic niobium methyl complexes, [TpMe2NbMe(L)(MeC=CMe)][BArf4] (L = OEt2, THF, 0 'Pr2, PMe2Ph and...

متن کامل

Computational Investigation of Structure and Reactivity of Methyl Hydrazinecarbodithioate

In this study, we theoretically investigated Methyl hydrazinecarbodithioate by quantum chemical calculations for geometry optimization, vibration frequencies, and electronic structure parameters. The geometry optimization by DFT, ab initio MP2 method and the frequency calculation by DFT method was performed at the highest available Pople style 6-311G++(3df,3pd) basis set level. The semi-emp...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of the American Chemical Society

سال: 2013

ISSN: 0002-7863,1520-5126

DOI: 10.1021/ja406721a